Why do alkyl iodides have highest boiling points among alkyl halides?
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Among isomeric alkyl halides, the boiling point decreases with an increase in branching in the alkyl group. 1-Chlorobutane (n-Butyl chloride) is a straight-chain isomer. It has the strongest interparticle forces. Hence it has the highest boiling point among all the isomers.
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