Why do mercury cell starts working when we rub it? [Electrochemistry]
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Answer:This is a small watch mercury battery. ... This helps prevent the collection of mercury into large droplets. During discharge, zinc oxidizes to zinc oxide, and mercuric oxide gets reduced to elemental mercury. A little extra mercuric oxide is put into the cell to prevent evolution of hydrogen gas at the end of its life
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As the overall reaction does not involve any ion in the solution whose concentration changes during its life period.
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