why do most ores occur in the form of oxides in earth crust
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Metals occur in nature in free as well as combined form. Metals having low reactivity show little affinity for air, moisture, carbon dioxide or other non-metals present in nature. Such metals may remain in elemental or native (free) state in nature. Such metals are called "noble metals" as they show the least chemical reactivity. For example gold, silver, mercury and platinum occur in free state. On the other hand, most of the metals are active and combine with air, moisture, carbon dioxide and non-metals like oxygen, sulphur, halogens, etc. to form their compounds, like oxides, sulphides, carbonates, halides and silicates. i.e., they occur in nature in a combined state. A naturally occurring material in which a metal or its compound occurs is called a mineral. A mineral from which a metal can be extracted economically is called an ore. An ore is that mineral in which a metal is present in appreciable quantities and from which the metal can be extracted economically. The main active substances present in nature, expecially in the atmosphere are oxygen and carbon dioxide. In the earth's crust, sulphur and silicon are found in large quantities. Sea-water contains large quantities of chloride ions (obtained from dissolved sodium chloride). Most avtive metals are highly electropositive and therefore exist as ions. It is for this reason that most of the important ores of these metals occur as (i) oxides (ii) sulphides (iii) carbonates (iv) halides and (v) silicates. Some sulphide ores undergo oxidation by air to form sulphates. This explains the occurrence of sulphate ores.
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