Chemistry, asked by karmveer9412, 2 months ago

why do transition metals form more stable capleres​

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Answered by havellshavells
0

Answer:

According to this model, transition-metal ions form coordination complexes because they have empty valence-shell orbitals that can accept pairs of electrons from a Lewis base. Ligands must therefore be Lewis bases: They must contain at least one pair of nonbonding electrons that can be donated to a metal ion.

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Answered by Anonymous
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Answer:

  • To illustrate my answer, I am going to use a modified version of the picture of a simplified molecular orbitals
  • In the left you can see the metal’s orbitals, on the right the group orbitals of six σ donors (assuming no π interactions of any kind). eg and t2g correspond to the metal’s d-orbitals, a1g is the 4s orbital and t1u are the 4p-orbitals.

  • Empty d-orbitals can thus be thought to help with coordination by stabilising the coordination compound. Completely filled d-orbitals (e.g. Zn2+) are contra productive and therefore zinc’s coordination chemistry is much like sodium’s.

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