Why do vapours of high boiling fractions condense first in the fractional column?
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The vapour rises through the fractionating column when the mixture is heated. Because ethanol is more volatile, the vapour contains more ethanol. The hot vapour condenses upon touching the cold glass beads. At the same time, there is continues rise of hot vapour up the fractionating column.
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because they ge enough coolness for getting into state of liquid
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