why does Boyle's temperature of different gases are different?
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Explanation:
Tb(Boyle's Temperature) = a/Rb
where, R is universal gas constant and a,b are vander wall constant.
Because, different gases have different values of a and b
Hence, Boyle's Temperature of different gases are different.
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Boyle's temperature of different gases are different:
- Boyle's temperature is calculated at low pressure when the gas deviates from the ideal behavior and behaves as a real gas.
- For an ideal gas, Boyle's temperature =
- Here, r is the universal gas constant and a and b are vanderwaal's constant.
- As a depends on forces of attraction while b gives the size of the molecule and different molecules have different values of a and b so, different gases have different Boyle's temperatures. The value of a and b also depends upon the molecular weight as well.
- For example, Ammonia and water molecule have hydrogen bonding. so, it will give a different value of Boyle's temperature than a molecule that does not have such a strong type of bonding.
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