Question

Why does steam burn more than boiling water

Answer 1

Phase changes require a lot more energy than just a temperature change. The energy required for water to go from a liquid to a gas is called the heat of vaporization. When steam (water in the gas phase) hits your skin, a lot of energy will be released as it condenses into a liquid, undergoing a phase change.
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Answer 2

that is because steam has more energy due to its laten heat of vaporisation.

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