why does the cyclopropyl methyl carbanion is more stable than cyclopropyl methyl carbocation
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It is commonly said, that a cyclopropane fragment behaves somewhat like a double bond. It can conjugate, and pass mesomeric effect similar to a double bond, but the donor orbital is σC−C instead of πC=C. Cyclopropane can be considered as a complex of a carbene and an alkene, where the carbene p orbital interacts with the π∗C=C orbital while the carbene sp2 orbital interacts with the πC=C orbital, so this 'virtual' double bond behaves somewhat like a normal double bond.
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meet /zpw-nrxj-pfq ....................
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