Why does the Sun appear reddish early in the morning?
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It is due to scattering of light. Most of the blue light is scattered away and longer wavelengths reach our eyes giving rise to reddish colour of the Sun.
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It is because that time, means during early morning,the sun is closer to the horizon. So the sunlight near the horizon passes through the denser layer and lights that having longer wavelengths reaches our eyes which includes red and orange colour and rest of the lights those having shorter wavelengths get scattered and that's why the sun appear reddish early in the morning during sunrise.
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