Why human being cannot digest cellulose for class 7?
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Polysaccharides are carbohydrate polymers consisting of tens to hundreds to several thousand monosaccharide units. All of the common polysaccharides contain glucose as the monosaccharide unit. Polysaccharides are synthesized by plants, animals, and humans to be stored for food, structural support, or metabolized for energy.
Cellulose:
The major component in the rigid cell walls in plants is cellulose. Cellulose is a linear polysaccharide polymer with many glucose monosaccharide units. The acetal linkage isbeta which makes it different from starch. This peculiar difference in acetal linkages results in a major difference in digestibility in humans. Humans are unable to digest cellulose because the appropriate enzymes to breakdown the beta acetal linkages are lacking. (More on enzyme digestion in a later chapter.) Undigestible cellulose is the fiber which aids in the smooth working of the intestinal tract.
Animals such as cows, horses, sheep, goats, and termites have symbiotic bacteria in the intestinal tract. These symbiotic bacteria possess the necessary enzymes to digest cellulose in the GI tract. They have the required enzymes for the breakdown or hydrolysis of the cellulose; the animals do not, not even termites, have the correct enzymes. No vertebrate can digest cellulose directly.
Even though we cannot digest cellulose, we find many uses for it including: Wood for building; paper products; cotton, linen, and rayon for clothes; nitrocellulose for explosives; cellulose acetate for films.
The structure of cellulose consists of long polymer chains of glucose units connected by a beta acetal linkage. The graphic on the left shows a very small portion of a cellulose chain. All of the monomer units are beta-D-glucose, and all the beta acetal links connect C # 1 of one glucose to C # 4 of the next glucose.
Cellulose - Chime in new window
Acetal Functional Group:
Carbon # 1 is called the anomeric carbon and is the center of an acetal functional group. A carbon that has two ether oxygens attached is an acetal.
The Beta position is defined as the ether oxygen being on the same side of the ring as the C # 6. In the chair structure this results in a horizontal or up projection. This is the same definition as the -OH in a hemiacetal
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