why is sodium amalgam used to prepare hydeogen instead of normal sodium
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Na(Hg), is an alloy of Mercury and sodium. The term amalgam is used for alloys, intermetallic compounds, and solutions (both solid solutions and liquid solutions) involving mercury as a major component. Sodium amalgam is often used in reactions as strong reducing agents with better handling properties compared to solid sodium. They are less dangerously reactive toward water and in fact are often used as an aqueous suspension.
Metallic sodium dissolves in mercury exothermically, i.e. with the release of heat, therefore, formation of sodium amalgam is famously dangerous for generating sparks.The process causes localised boiling of the mercury and for this reason the formation is usually conducted in a fume hood and often performed using air-free techniques, such as synthesis under anhydrous liquid paraffin. Sodium amalgam may be prepared in the laboratory by dissolving sodium metal in mercury or the reverse.Sodium amalgams can be purchased from chemical supply houses.
Metallic sodium dissolves in mercury exothermically, i.e. with the release of heat, therefore, formation of sodium amalgam is famously dangerous for generating sparks.The process causes localised boiling of the mercury and for this reason the formation is usually conducted in a fume hood and often performed using air-free techniques, such as synthesis under anhydrous liquid paraffin. Sodium amalgam may be prepared in the laboratory by dissolving sodium metal in mercury or the reverse.Sodium amalgams can be purchased from chemical supply houses.
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