Why is the oxygen-nitrogen proportion of 1:4 in the air appropriate?
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The vapour pressure of air over water is 10 atm.
The partial pressure of nitrogen =PN2=10079×10=7.9atm=7.9×760mmHg=6004 mm Hg
The partial pressure of oxygen PO2=10020×10=2.0atm=2.0×760mmHg=1520 mm Hg
According to Henry's law,
PN2=KH(N2)×XN2
XN2=KH(N2)PN2=6.51×1076004=9.22×10−5
XO2=KHO
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