Question

Why is Vapour pressure of C2H5OC2H5 higher than that of CCl4

Answer 1

vaporization doesn't exactly stop (at the microscopic level), but the rates of molecules passing from liquid to gas and gas to liquid become equal.

"Boils" describes a vaporization in which bubbles of vapor are nucleated, grow, rise through the liquid, and 'pop' into the empty space above the liquid surface. Whether a net vaporization is "boiling" or not depends on the pressure differential to that at liquid/gas equilibrium, presence of nucleation sites (e.g. boiling chips, rough surfaces, etc.), "hydrostatic" pressure at the potential nucleation sites, and maybe other factors.

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