Chemistry, asked by 2Vaishali1, 1 year ago

why it is difficult to remove chlorine as nucleophilic from benzene rather than alkyl Halide

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Answered by harismitha
1
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I must say, not only chloro-benzene, but all type of arylhalides are less reactive than alkyl halides. Any Sn1 or Sn2 type reaction for halides involves the breaking of carbon-halogen bond in some stage. But it is very difficult to break the carbon-halogen bond of any arylhalide. It’s because the carbon-halogen bond in arylhalide is much more Stronger than that is in alkyl halide. Actually one loan pair of halogens is contributed to the benzene ring to form the resonant electron flow in benzene ring. Thus making it less reactive towards nucleophillic reactions.


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