Why less volatile liquid condenses more readily than more volatile liquid?
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... of a vapor to condense into a liquid or solid; less volatile substances will more readily condense from a vapor than highly volatile ones.
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Chemical Bonds contribute to volatility
The major attractive forces between molecules in a liquid are called hydrogen bonds. Less hydrogen bonding is expected between molecules of a volatile liquid compared with other less volatile liquids. ... Compared to methoxymethane, ethanol is not nearly as volatile.
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