Chemistry, asked by Hrithik7423, 1 year ago

Why oxygen shows catenation behaviour less than sulphur?

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Answered by Anonymous
5
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⭐⭐⬅️ Answer ➡️➡️➡️➡️Oxygen is small in size and the lone pair on oxygen repel the bond pairs of O-O bond to larger extent than the lone pairs on sulphur in S-S bond. The S-S bond energy 213K/J mol therefore bond strength is more compared to O-O bond energy 138k/J mol. ... Hencesulphur has great tendency forcatenation than oxygen.
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Answered by Anonymous
8

Oxygen is small in size and the lone pair on oxygen repel the bond pairs of O-O bond to larger extent than the lone pairs on sulphur in S-S bond. The S-S bond energy 213K/J mol therefore bond strength is more compared to O-O bond energy 138k/J mol. ... Hence sulphur has great tendency for catenation than oxygen.

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