Why para toluidine is more basic than meta toluidine?
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Explanation:
the CH₃ groups shifts electrons towards the benzene ring from para position in p-toluidine, the electron density of the ring increases, and so te lone pair of N is readily available, which makes it a good base than m-toluidine, in which the CH₃ group attached in meta position cannot show +I effect strongly, .
het085185:
But why not considered +H effect at para position?
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2
Answer:
As the CH₃ groups shifts electrons towards the benzene ring from para position in p-toluidine, the electron density of the ring increases, and so te lone pair of N is readily available, which makes it a good base than m-toluidine, in which the CH₃ group attached in meta position cannot show +I effect strongly, and the ...
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