Why potassium permanganate shows d1 electronic configuration?
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Let’s take a look at a qualitative MO scheme for a tetrahedric transition metal complex whose ligands have three p-type orbitals each. On the left of figure 1 you have the metal orbitals (3d, 4s and 4p) and on the right the twelve degenerate ligand p-orbitals (transform as a1+e+t1+2t2). Only orbitals of the same symmetry will mix, so the t1 ones stay where they are originally. I have colour-coded both the t2 (red) and e (blue) orbitals
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Potassium permanganate | KMnO4 | CID 516875 - structure, chemical names, physical and chemical ... Pure Light E 2 ... Potassio ( permanganato di)
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