Why solutions deviate from law?Raoult's
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If the solute and solvent are not as tightly bound to each other as they are to themselves, then the solution will show a positive deviation from Raoult's law because the solvent molecules will find it easier to escape from solution into the gas phase.....
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can also be applied to an ideal binary solution in which both components are volatile. A binary solutions is said to be ideal when there is no absorption or evolution of heat when the two volatile liquid components are mixed to form the solution. and represent the mole fraction of the two components '' and '' in liquid respectively, we have, from Raoult's law, the following deletions for each of the components.
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