Why when the match stick on striking gives a sparkle and the match stick lights.
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When you rub the head of the matchstick on the striking surface of the matchbox, some heat is generated due to the friction. This heat breaks a small part of the red phosphorus chain. After that some red phosphorus transforms into white phosphorus. White phosphorus is a highly volatile chemical and ignites in the air.
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The striker on a match pack or box also contains glass powder and sand, in addition to red phosphorus. The glass powder and sand provide friction that helps create the heat needed to turn a bit of the red phosphorus into white phosphorus, which is more volatile and ignites more easily.
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