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Equation for real gas is -: (p+an^2/v^2) (v-nb)=Rt
As pressure is high hence volume is less so we can take (p+an^2/v^2) ~ p. But volume =v-nb
So equation is = pv-pnb=Rt
Pv/Rt = 1+Pnb/Rt
But moles=1 so becomes = 1+ Pb/RT
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