Woll krishner reaction
Answers
The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step. As such, there is no obvious retron for this reaction. Originally reported by Nikolai Kischner in 1911 and Ludwig Wolff in 1912 it has been applied to the total synthesis of scopadulcic acid B aspidospermidine and dysidiolide
→The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups.
→In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.
→The reduction of aldehydes and ketones to alkanes.
→Condensation of the carbonyl compound with hydrazine forms the hydrazone, and treatment with base induces the reduction of the carbon coupled with oxidation of the hydrazine to gaseous nitrogen, to yield the corresponding alkane.
Oraganic Redox Reaction