write a chemical test to distinguish between formal dehyde and accetaldehyde.
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Solution. Acetaldehyde, when heated with I2 and NaOH, gives a yellow precipitate of iodoform (Iodoform test) whereas formaldehyde does not give a yellow precipitate of iodoform.
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Explanation:
Ionization test is used for differentiation of acetaldehyde and formaldehyde.
H
3
CCHO+HNaOH+3I
2
⟶CH
3
I
3
+HCOONa+3NOI+3H
2
O
Acetaldehyde gives Iodoform test.
HCHO+4NaOH+3I
2
⟶ No Iodoform.
Formaldehyde does not gives Iodoform test.
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