write a short note on vacancy or hole theory and free volume theory
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A QUASI-CHEMICAL theory of the liquid state can be built up by incorporating the cluster idea of the Band-Frenkel theory of condensing systems into the Eyring theory ; thus the free volume of the liquid molecules will become an adjustable parameter and a function of temperature. A similar theory had already been advanced by Fürth1, who considered the liquid as a continuum permeated by holes, and attributed the properties of the liquid as due to their presence.
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