Question

Write chemical equations for the reaction that take place during smelting of haematite

Answer 1

The blast furnace

Iron is extracted from iron ore in a huge container called a blast furnace. Iron ores such as haematitecontain iron(III) oxide, Fe2O3. The oxygen must be removed from the iron(III) oxide in order to leave the iron behind. Reactions in which oxygen is removed are called reduction reactions.

Carbon is more reactive than iron, so it can displace iron from iron(III) oxide. Here are the equations for the reaction:
Iron(III) oxide + carbon → iron + carbon dioxide
2Fe2O3(s) + 3C(s) → 4Fe(l) + 3CO2(g)
In this reaction, the iron(III) oxide is reduced to iron, and the carbon is oxidised to carbon dioxide.
In the blast furnace, it is so hot that carbon monoxide can be used, in place of carbon, to reduce the iron(III) oxide:
iron(III) oxide + carbon monoxide → iron + carbon dioxide
Fe2O3(s) + 3CO(s) → 2Fe(l) + 3CO2(g)

Raw materials for the reaction

Iron ore (haematite)Iron(III) oxideA compound that contains ironCokeCarbonBurns in air to produce heat, and reacts to form carbon monoxide (needed to reduce the iron oxide)LimestoneCalcium carbonateHelps to remove acidic impurities from the iron by reacting with them to form molten slagAirOxygenAllows the coke to burn, and so produces heat

Removing impurities

The calcium carbonate in the limestone thermally decomposes to form calcium oxide.
calcium carbonate → calcium oxide + carbon dioxide
CaCO3(s) → CaO(s) + CO2(g)
The calcium oxide then reacts with silica (sand) impurities in the haematite, to produce slag - which is calcium silicate.
calcium oxide + silica → calcium silicate
CaO(s) + SiO2(s) → CaSiO3(l)
This reaction is a neutralisation reaction. Calcium oxide is basic (as it is a metal oxide) and silica is acidic (as it is a non-metal oxide).

Answer 2

Answer: the equations are given below.

Explanation:

Haematite is an ore which is used to extract iron. The formula for this ore is $Fe_2O_3$.

In iron blast furnace, several chemical reactions takes place which leads to the formation of desired product which is iron. The coke which is another form of carbon reacts with oxygen to produce carbon dioxide. The $CO_2$ which is produced then reacts with more amount of coke to produce carbon monoxide.

$C+O_2\rightarrow CO_2$

$CO_2+C\rightarrow 2CO$

Carbon monoxide formed acts like a reducing agent and thus reacts with the iron ore to give molten iron, which is settled at the bottom of the furnace where it is collected.

$Fe_2O_3+3CO\rightarrow 2Fe+3CO_2$

The limestone which is present in the furnace then decomposes and forms calcium oxide. This acts as a fluxing agent and then combines with impurities to form slag, which then floats to the top of the molten iron and thus can be removed.

$CaO+SiO_2\rightarrow CaSiO_3$

Thus, the equations that take place during the smelting of haematite is given above.