Chemistry, asked by basutalawar22, 10 months ago

write Gibbs equation and explain the terms​

Answers

Answered by Anonymous
8

Heyy Mate Here Is ur Answer....

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.he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.

he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.Equation

he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]

he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]{\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},} {\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},}

he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]{\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},} {\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},}where H is the enthalpy, T the absolute temperature and G the Gibbs free energy of the system, all at constant pressure p. The equation states that the change in the G/T ratio at constant pressure as a result of an infinitesimally small change in temperature is a factor H/T2.

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Answered by preety89
11

Let us write and explain the Gibbs equation

Explanation:

Gibbs free energy  

  • It is the energy available in the system that can be converted into useful work .It is    denoted by G
  • It is state function  
  • It is a Extensive property  
  • It is given by   equation  G = H – TS
  • Also written as :
  • ΔG=H-TΔS

In this : G =  Gibbs free energy

H = Enthalpy

T= temperature

S = entropy

Let us define all :

"G " is It is defined as the amount of energy for a system that can be converted into useful work

It actually determines the spontaneity of a reaction i.e

  • If G is +ve - reaction is non -spontaneous
  • If G is -ve --reaction is spontaneous
  • If G=0 --> reaction is at equilibrium  

This equation takes into account both the concepts (a)energy factor and other (b) entropy factor ≡

Enthalpy (H)

it is sum of internal energy and   P-V work.

Given by H=U +PV

or ΔH=ΔU+PΔV

Entropy: -Is “measure if degree of randomness.”It is   denoted by S,it is a state function and extensive property .

Given as ΔS=Sproducts -S reactants

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