write Gibbs equation and explain the terms
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.he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.
he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.Equation
he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]
he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]{\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},} {\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},}
he Gibbs–Helmholtz equation is a thermodynamic equation used for calculating changes in the Gibbs energy of a system as a function of temperature.EquationThe equation is:[1]{\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},} {\displaystyle \left({\frac {\partial ({\frac {G}{T}})}{\partial T}}\right)_{p}=-{\frac {H}{T^{2}}},}where H is the enthalpy, T the absolute temperature and G the Gibbs free energy of the system, all at constant pressure p. The equation states that the change in the G/T ratio at constant pressure as a result of an infinitesimally small change in temperature is a factor H/T2.
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Let us write and explain the Gibbs equation
Explanation:
Gibbs free energy
- It is the energy available in the system that can be converted into useful work .It is denoted by G
- It is state function
- It is a Extensive property
- It is given by equation G = H – TS
- Also written as :
- ΔG=H-TΔS
In this : G = Gibbs free energy
H = Enthalpy
T= temperature
S = entropy
Let us define all :
"G " is It is defined as the amount of energy for a system that can be converted into useful work
It actually determines the spontaneity of a reaction i.e
- If G is +ve - reaction is non -spontaneous
- If G is -ve --reaction is spontaneous
- If G=0 --> reaction is at equilibrium
This equation takes into account both the concepts (a)energy factor and other (b) entropy factor ≡
Enthalpy (H)
it is sum of internal energy and P-V work.
Given by H=U +PV
or ΔH=ΔU+PΔV
Entropy: -Is “measure if degree of randomness.”It is denoted by S,it is a state function and extensive property .
Given as ΔS=Sproducts -S reactants