Question

Write IUPAC name of the complex Co(en)2(NO2)Cl+ . what type of structural isomerism is shown by this complex

Answer 1

Answer:

IUPAC name of [Co(en)2(ONO)Cl]C l is chloridobis (ethane-1, 2-diamine) nitro-O- cobalt (III) chloride

Explanation:

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Answer 2

The IUPAC name of Co(en)2(NO2)Cl+ is diaquacopper(II) nitrito chloride. The structural isomerism in this is:

• Coordination isomerism- In coordination compounds, which are substances with a core metal ion (also known as a coordination centre) that is bonded to one or more ligands.
• A ligand is a molecule or an ion that forms a coordinate covalent connection with a metal ion, sharing an electron pair in the process.
• Different isomers of the same metal ion and ligand are produced by different spatial arrangements in coordination isomerism. This is due to the fact that the ligands can be repositioned around the central metal ion without altering the compound's chemical makeup.
• The nitrito ligands (NO2-) can, for instance, be positioned trans (across) or cis (next to) to one another in the complex Co(en)2(NO2)Cl+.
• Two distinct coordination isomers are produced as a result, each of which has unique physical and chemical characteristics.

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