write Kolbe's electrolytic mechanism for propanoic acid
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Kolbe Electrolysis
The electrochemical oxidative decarboxylation of carboxylic acid salts that leads to radicals, which dimerize. It is best applied to the synthesis of symmetrical dimers, but in some cases can be used with a mixture of two carboxylic acids to furnish unsymmetrical dimers.
Mechanism of the Kolbe Electrolysis
Side products:
The formation of side products depends on the ease of the follow-up oxidation which leads to carbenium ions, and their subsequent rearrangement:
Answer:
Organic Chemistry Portal
Reactions >> Name Reactions
Further Information
Literature
Related Reactions
Synthesis of alkanes
Kolbe Electrolysis
The electrochemical oxidative decarboxylation of carboxylic acid salts that leads to radicals, which dimerize. It is best applied to the synthesis of symmetrical dimers, but in some cases can be used with a mixture of two carboxylic acids to furnish unsymmetrical dimers.