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Answers
answer of 23 is 3.it is prepared by contact process
Explanation:
23) Which of the following statement is incorrect about sulphuric acid -
a) In water it mainly ionises in 1st step
b) B.P. is high due to strong H-bond
c) It is prepared by contact process
d) Because of high votality it's used to prepare other acids. ✔
Explanation :-
- Sulphuric acid is a dibasic acid. In aqueous solution it ionises in two steps, but it mainly ionises in 1st step.
- Sulphuric acid boils at 611 K and freeze at 283 K. Boiling point is high because of strong intermolecular H-bonds.
- Sulphuric acid is manufactured by contact process.
- Sulphuric acid is low votality. Due to its low votlality, it is used to manufacture more volatile acids.
24) In which of the following nitrogen undergoes oxidation ?
a) N2 to NH3
b) N2O4 to NO2
c) NO3- to N2O5
d) NO2- to NO3- ✔
Explaination :-
Let's Check all option and see that which is reducing and which one is oxidising.
Option a)
O.N. of N2 is 0 & NH3 is -3.
Calculation :-
NH3 :-
x + 1×3 = 0
x = -3
Hence, O.N. is decreasing. It means, Reduction.
Option b)
O.N. of N2O4 & NO2 is +4
Calculation :-
N2O4 :-
2x - 2×4 = 0
2x = 8
x = 4
And
NO2 :-
x -2×2 = 0
x = 4
Hence,
O.N. is neither decreasing nor increasing. It means, Not reduction nor oxidation.
Not reduction nor oxidation. Option c)
O.N. of NO3- & N2O5 is +5
Calculation :-
NO3- :-
x - 2×3 = -1
x = 6 - 1
x = 5
And
N2O5 :-
2x - 2×5 = 0
2x = 10
x = 5
Hence,
O.N. is neither decreasing nor increasing. It means, Not reduction nor oxidation.
Not reduction nor oxidation. Option d)
O.N. of NO2- is
Calculation :-
NO2- :-
x - 2×2 = -1
x = 4 - 1
x = 3
And
NO3- :-
x - 2×3 = -1
x = 6 - 1
x = 5
Hence,
O.N. is increasing from 3 to 5.
It means, Oxidation.
Therefore,
Option D is correct.