Write schrödinger equation and mention all the notations
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In quantum mechanics, the Schrödinger equation is a mathematical equation that describes the changes over time of a physical system in which quantum effects, such as wave–particle duality, are significant. These systems are referred to as quantum (mechanical) systems. The equation is considered a central result in the study of quantum systems, and its derivation was a significant landmark in the development of the theory of quantum mechanics. It was named after Erwin Schrödinger, who derived the equation in 1925, and published it in 1926, forming the basis for his work that resulted in him being awarded the Nobel Prize in Physicsin 1933.[1][2]
In classical mechanics, Newton's second law(F = ma) is used to make a mathematical prediction as to what path a given physical system will take over time following a set of known initial conditions. Solving this equation gives the position, and the momentum of the physical system as a function of the external force F on the system. Those two parameters are sufficient to describe its state at each time instant. In quantum mechanics, the analogue of Newton's law is Schrödinger's equation for a quantum system (usually atoms, molecules, and subatomic particles whether free, bound, or localized). The equation is mathematically described as a linear partial differential equation, which describes the time-evolution of the system's wave function (also called a "state function").[3]:1–2
The concept of a wavefunction is a fundamental postulate of quantum mechanics, that defines the state of the system at each spatial position, and time. Using these postulates, Schrödinger's equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by the exponential of a self-adjoint operator, which is the quantum Hamiltonian. This derivation is explained below.
In the Copenhagen interpretation of quantum mechanics, the wave function is the most complete description that can be given of a physical system. Solutions to Schrödinger's equation describe not only molecular, atomic, and subatomic systems, but also macroscopic systems, possibly even the whole universe.[4]:292ff Schrödinger's equation is central to all applications of quantum mechanics including quantum field theorywhich combines special relativity with quantum mechanics. Theories of quantum gravity, such as string theory, also do not modify Schrödinger's equation.
The Schrödinger equation is not the only way to study quantum mechanical systems and make predictions, as there are other quantum mechanical formulations such as matrix mechanics, introduced by Werner Heisenberg, and path integral formulation, developed chiefly by Richard Feynman. Paul Diracincorporated matrix mechanics and the Schrödinger equation into a single formulation.
In classical mechanics, Newton's second law(F = ma) is used to make a mathematical prediction as to what path a given physical system will take over time following a set of known initial conditions. Solving this equation gives the position, and the momentum of the physical system as a function of the external force F on the system. Those two parameters are sufficient to describe its state at each time instant. In quantum mechanics, the analogue of Newton's law is Schrödinger's equation for a quantum system (usually atoms, molecules, and subatomic particles whether free, bound, or localized). The equation is mathematically described as a linear partial differential equation, which describes the time-evolution of the system's wave function (also called a "state function").[3]:1–2
The concept of a wavefunction is a fundamental postulate of quantum mechanics, that defines the state of the system at each spatial position, and time. Using these postulates, Schrödinger's equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by the exponential of a self-adjoint operator, which is the quantum Hamiltonian. This derivation is explained below.
In the Copenhagen interpretation of quantum mechanics, the wave function is the most complete description that can be given of a physical system. Solutions to Schrödinger's equation describe not only molecular, atomic, and subatomic systems, but also macroscopic systems, possibly even the whole universe.[4]:292ff Schrödinger's equation is central to all applications of quantum mechanics including quantum field theorywhich combines special relativity with quantum mechanics. Theories of quantum gravity, such as string theory, also do not modify Schrödinger's equation.
The Schrödinger equation is not the only way to study quantum mechanical systems and make predictions, as there are other quantum mechanical formulations such as matrix mechanics, introduced by Werner Heisenberg, and path integral formulation, developed chiefly by Richard Feynman. Paul Diracincorporated matrix mechanics and the Schrödinger equation into a single formulation.
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