Write the balanced overall equation for the following process (equation 3) and calculate ∆HoveralI.
(1) N2 (g) + O2(g) → 2NO(g) ∆H = 180.6 kJ
(2) 2NO(g) + O2(g) → 2NO2(g) ∆H = - 114.2 kJ
(3) ∆Hoverall=?
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The balanced reaction is given below
- Adding both the equations -
N2 (g) + O2(g) → 2NO(g) ∆H = 180.6 kJ
2NO(g) + O2(g) → 2NO2(g) ∆H = - 114.2 kJ
- Final reaction will be -
N2 (g) + 2O2(g) → 2NO2(g)
∆H overall= 180.6 + ( - 114.2)
∆H overall= 66.4 kJ
- The calculation of overlap ∆H is in accordance with Hess's Law. The Hess's Law states that enthalpy of a reaction is sum of enthalpy of individual steps of reaction.
- Enthalpy is defined as "measure of heat in a system".
- In the reaction, N2 is nitrogen, O2 is oxygen, NO is nitric oxide and NO2 is nitrogen dioxide.
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