write the Expression in reversible is theremal free expansion of ideal gas
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For isothermal reversible and irreversible changes; equation 1 can be expressed as: Isothermal reversible change: q = -w = pex(Vf-Vi) Isothermal reversible change: q = -w = nRTln (Vf/Vi) = 2.303 nRT log (Vf/Vi) Adiabatic change: q =0, ∆U = w.
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Since the First Law of Thermodynamics states that ΔU = Q + W (IUPAC convention), it follows that Q = −W for the isothermal compression or expansion of ideal gases.
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