Write the names of the structures below and inform the halide with 12,2° and 3°. CH, CI
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12th
Chemistry
Haloalkanes and Haloarenes
Classification and Nomenclature of Haloalkanes and Haloarenes
Name the following halides ...
CHEMISTRY
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
i) (CH
3
)
2
CHCH(Cl)CH
3
ii) CH
3
CH
2
CH(CH
3
)CH(C
2
H
5
)Cl
iii) CH
3
CH
2
C(CH
3
)
2
CH
2
I iv) (CH
3
)
3
CCH
2
CH(Br)C
6
H
5
v) CH
3
CH(CH
3
)CH(Br)CH
3
vi) CH
3
C(C
2
H
5
)
2
CH
2
Br
vii) CH
3
C(Cl)(C
2
H
5
)CH
2
CH
3
viii) CH
3
CH=C(Cl)CH
2
CH(CH
3
)
2
ix) CH
3
CH=CHC(Br)(CH
3
)
2
x) p−ClC
6
H
4
CH
2
CH(CH
3
)
2
xi) m−ClCH
2
C
6
H
4
CH
2
C(CH
3
)
3
xii) o−Br−C
6
H
4
CH(CH
3
)CH
2
CH
3
MEDIUM
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VIDEO EXPLANATION
ANSWER
The IUPAC names of various compounds are given below in order:
(1) 2-Chloro-3-methylbutane (secondary alkyl halide)
(ii) 3-Chloro-4-methylhexane (secondary alkyl halide)
(iii) 1-Iodo-2,2-dimethylbutane (primary alkyl halide)
(iv) 1-Bromo-3,3-dimethyl-1-phenylbutane (secondary benzyl halide)
(v) 2-Bromo-3-methylbutane (secondary alkyl halide)
(vi) 1-Bromo-2-ethyl-2-methylbutane (primary alkyl halide)
(vii) 3-Chloro-3-methylpentane (tertiary alkyl halide)
(viii) 3-Chloro-5-methylhex-2-ene (vinyl halide)
(ix) 4-Bromo-4-methylpent-2-ene (allyl halide)
(x) 1-Chloro-4-(2-methylpropyl) benzene (aryl halide)
(xi) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene (primary benzyl halide)
(xii) 1-Bromo-2-(1-methylpropyl) benzene (aryl halide)