Write the reaction of Zn with HNO3
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Zn + HNO3 --------->ZNO3 +H2O
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⏯️⏯️With cold, dilute nitric acid, zinc liberates nitric oxide (NO), along with soluble zinc nitrate and water.
3 Zn + 8 HNO3 = 3 Zn(NO3)2 + 2 NO + 4 H2O
⏯️⏯️But with hot, concentrated HNO3, reddish brown nitrogen dioxide (NO2) is produced.
Zn + 4 HNO3 = Zn(NO3)2 + 2 NO2 + 2 H2O
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