Question

write the Reactivity of aldehydes and ketones​

Answer 1

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Reactivity of aldehydes and ketones is due to the polarity of carbonyl group which results in electrophilicity of carbon. In general, aldehydes are more reactive than ketones toward nucleophilic attack. This can be well explained in terms of both the electronic effects and steric effect.

1. Influence of electronic effects :

Alkyl groups have electron donating inductive effect (+I). A ketone has two electron donating alkyl groups bonded to carbonyl carbon which are responsible for decreasing its positive polarity and electrophilicity. In contrast, aldehydes have only one electron donating group bonded to carbonyl carbon. This makes aldehydes more electrophilic than ketones.

2. Steric effects :

Two bulky alkyl groups in ketone come in the way of incoming nucleophile. This is called steric hindrance to nucleophilic attack. On the other hand, nucleophile can easily attack the carbonyl carbon in aldehyde because it has one alkyl group and is less crowded or sterically less hindered . Hence aldehyde are more easily attacked by nucleophiles.