write the statement of bohr's second postulate of quantization. Describe De Broglie explanation of Bohr's second postulate of quantisation. Write its two limitations
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DE BROGLIE'S JUSTIFICATION OF BOHR'S ASSUMPTION - DEFINITION
De Broglie came up with an explanation for why the angular momentum might be quantized in the manner Bohr assumed it was. De Broglie realized that if you use the wavelength associated with the electron, and assume that an integral number of wavelengths must fit in the circumference of an orbit, you get the same quantized angular momenta that Bohr did.
The circumference of the circular orbit must be an integral number of wavelengths:
2πr=nλ=pnh (λ=ph)
The momentum, p, is simply mv as long as we're talking about non-relativistic speeds, so this becomes:
2πr=mvnh
Rearranging this a little gives the Bohr relationship:
Lr=mvr=2πnh
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