write the Stoichiometric point defects
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Stoichiometric point defects : Chemical formula of a compound shows fixed ratio of number of atoms or number of cations and anions. This fixed ratio is the stoichiometry of the compound.
In stoichiometric defect, the stoichiometry remains unchanged. In other words, the ratio of number of atoms or number of cations and anions of compound remains the same as represented by its chemical formula.
There are four types of stoichiometric point defects: vacancy defect, self interstitial defect, Schottky defect and Frenkel defect.
✶ STOICHIOMETRIC DEFECT ✶
In this kind of point defect, the ratio of positive and negative ions (Stoichiometric) and electrical neutrality of a solid is not disturbed.
Sometimes it is also known as intrinsic or thermodynamic defects.
Fundamentally, they are of two types:
➜Vacancy defect: When an atom is not present at their lattice sites, then that lattice site is vacant and it creates a vacancy defect. Due to this, the density of a substance decreases.
➜Interstitial defect: It is a defect in which an atom or molecule occupies the intermolecular spaces in crystals. In this defect, the density of the substance increases.
A non-ionic compound mainly shows vacancy and interstitial defects. An ionic compound shows the same in Frenkel and Schottky defect.