Chemistry, asked by yshrikant698, 1 month ago

Write the structure of Tetracyanonickelate (II)ion​

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Answered by hemntmali2001
0

Answer:

structure of tetracyano nickelate(II)ion

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Answered by nirman95
2

Structure of Tetracyanonickelate (II) ion:

First of all, the central metal is Ni^{+2}, as it is mentioned Ni (II) :

CN- is a strong field liga{n}d, so electronic configuration of Ni(+2) in presence of CN-

 {Ni}^{ + 2}  : (Ar) \: 3 {d}^{8}

 \implies {Ni}^{ + 2}  : (Ar)  \:  \boxed{ \uparrow \downarrow } \:  \boxed{  \uparrow \downarrow|  \uparrow \downarrow | \uparrow \downarrow| -  |  - }  \: \boxed{ - }  \: \boxed{ -  | -  |   - }

So, electrons from CN- will be inserted into 3d, 4s, and 4p orbital.

So, hybridisation will be : sp.

HENCE, STRUCTURE WILL BE TETRAHEDRAL.

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