0.73. Select the incorrect statement.
(a) Carbonyl compounds are at-
tacked by nucleophiles
(b) All aldehyde has a greater partial
positive charge on its carbonyl
carbon
(c) Protonation of a carbonyl com-
pound decreases electrophilic
nature and thus nucleophilic attack
is retarded
(d) Hydration of CC13CHO is more
than that of CH3CHO
Answers
Answer:
D is the answer
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Answer:
The incorrect statement., among the following are as under-
Explanation:
(a)The sentence " Carbonyl compounds are attacked by nucleophiles" is-
(a) correct .
The carbonyl group provides a site for nucleophilic addition or nucleophilic attack and increases the acidity of the hydrogen atoms which are attached to alpha carbon.
(b) The sentence "All aldehyde has a greater partial positive charge on its carbonyl carbon" is-
(b) correct.
In aldehydes ,the carbonyl carbon generally has more partial positive charge than in ketones as the electron-donating nature of alkyl groups. Aldehydes have only one e- donor group while ketones have two.
(c)The sentence is- "Protonation of a carbonyl com-pound decreases electrophilic nature and thus nucleophilic attack is retarded" is-
(c) correct
Formely, protonation of the carbonyl group at the oxygen takes place because of excess H+ all around. Once protonation has occurred, nucleophilic attack by the nucleophile finishes the addition reaction.
(d) The sentence -"Hydration of CC13CHO is more than that of CH3CHO" is-
(d) incorrect
This statement is incorrect.
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