1) The bond length (R) in diatomic molecules can be easily obtained from spectroscopic mea-
surements, in which the one measuures excitation energies that are related to the moment
of inertia
I = R2
where the reduced mass is defined as
MAMB
=
та + тв
and mA and me are the masses of individual atoms constituting the molecule.
A If the wave number of the rotational transition L = 0 + 1 of HBr molecule is 16.93 cm!
calculate the bond length of HBr.
B Use the result from the previous answer and calculate the energy of L = 5 6 transition
in cm-'.
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