10.Assuming that the vibration frequency
'v'of atoms in a crystal depends on the atomic mass m , the atomic spacing
'alpha' and compressibility 'beta', find an expression for frequency.
Given [
beta]=M-1
LT2
.
Answers
Given:
Assuming that the vibration frequency 'v'of atoms in a crystal depends on the atomic mass m , the atomic spacing 'alpha' and compressibility 'beta'.
Given [beta]=M-1 LT2
To find:
Find an expression for frequency.
Solution:
From given, we have an expression for the vibration frequency 'v'.
v ∝ m^x α^y β^z
⇒ v = k m^x α^y β^z
Using the units of above, we have,
[T^{-1}] = [M] ^x [L] ^y [M^{-1} L T^{2}] ^z
upon simplifying, we get,
[T^{-1}] = [M]^{x-z} [L]^{y-z} [T]^{2z}
comparing LHS and RHS, we have,
-1 = 2z
z = -1/2
x - z = 0
x = z
x = -1/2
y + z = 0
y = -z
y = 1/2
v = k m^{-1/2} α^{1/2} β^{-1/2}
v = √ {α/βm}
Hence the expression.
But we have the dimensional expression for beta as, [beta]=M L-1T-2
If we use this expression, then we have,
v = k m^{-1/2} α^{1/2} β^{1/2}
v = √ {αβ/m}