150 ml of n/10 HCL are required to react completely with 1.0 grams of a symbol of a limestone caco3 the percentage purity of the sample is
Answers
Reaction:
CaCO3+2HCl⟶CaCl2+H2O+CO2
Number of milli equivalence of HCl used initially is 15
Number of milli moles of HCl used initially is 152
2 moles of HCl reacts with 1 mole of CaCO3.
So amount of calcium carbonate is 154×10−3 mol=38 g
But answer given is 75%
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Jan 4 '16 at 7:31
Aditya Dev
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Feb 27 '18 at 13:26
Gaurang Tandon
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We know that 2 moles of HCl are required to react completely with 1 mole of CaCO3. We find out the number of moles of HCl in 150ml 0.1M HCl (0.1NHCl=0.1MlHCl), which is 0.015 moles. Now the amount of CaCO3 reacted is (0.0152) = 0.0075 moles.
Amount of CaCO3 in gms =
0.0075 moles×100 (mol.wt of CaCO3)=0.75g
...implying the purity is 75%.