2.56 g of sulphur in 100 g of cs2 has depression in freezing point of 0.010c kf = 0.1c (molal)1. Hence atomicity of sulphur in the solution is
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given,
mass of sulphur, w = 2.56 g
mass of solvent , W = 100g
depression in freezing point , ∆Tf = 0.01 °C
and Kf = 0.1°C/(molal)
using formula,
where M is molar mass of sulphur
= 0.1 × 2.56 × 1000/(0.01 × 100)
= 256g
hence, molar mass of sulphur = 256g/mol
now, atomicity = molar mass/atomic mass
= 256/32 = 8
hence, answer is 8
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