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class 12 chemistry
solutions chapter
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Explanation:
The molar mass M2 of non-volatile substance can be calculated from the following formula.
p0-p/p0=W2×M1/W1+M2
Here, p0 vapour pressure of acetone and p is the vapour pressure of the solution.
.
M1 and W 1 are the molar mass and mass of acetone.
M2 and W2are the molar mass and mass of a non-volatile substance.
Substitute values in the above expression.
185-183/185=1.2×58/100×M2
Hence, M2 =64.38g/mol.
Thus, the molar mass of the non-volatile substance is 64 g/mol (approximately).
Hence, the correct option is B
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