3. The solubility of lead iodide in water is 0.63 g/litre. Calculate the solubility product of lead iodide. Atof Pb = 207, I = 127)
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Explanation:
PbI
2
⇌Pb
2+
+2I
−
x 2x
given solubility of PbI
2
is 0.7
L
g
also, molar mass of PbI
2
=461.2g/mol
⇒[PbI
2
]=
461.2
0.7
mol/Litre=1.5×10
−3
solubility product, K
sp
=x(2x)
2
K
sp
=4x
3
K
sp
=4(1.5×10
−3
)
3
∴ Solubility product of PbI
2
=135×10
−9
mol
2
/lit
2
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