40 ml of a mixture of ch4 and co2 undergoes complete combustion with 80 ml of o2. X cal of reduction in volume were observed when the gaseous mixture was passed through alkaline pyrogallol 20 ml of reduction was absorbed the value of X and volume of co2 in the original mixture will be
Answers
Let volume of CO, CH4 and Ne be x, y and z respectively.
CO + 1/2O2 CO2 .....(1)
here it is clear that x volume of CO reacts with x/2 volume of O2 and produces sx volume of CO2
and CH4 + 2O2 CO2 + 2H2O (l).....(2)
here it is clear that y volume of CH4 reacts with 2y volume of O2 and produces y volume of CO2.
now remaining volume of O2 = 10 - x/2 - 2y
volume after reaction,
volume of CO2 [eq(1)] + volume of CO2 [eq(2)] + volume of oxygen remaining + volume of Ne = 36.5 ml
or, x + y + 10 - x/2 - 2y + z = 36.5 ml
or, x/2 - y + z = 26.5 ml ......(i)
given, volume of Co + volume of CH4 + volume of Ne = 40ml
or, x + y + z = 40ml.....(ii)
we know, KOH reduces CO2
so, volume of CO2 [eq(1) ] + volume of CO2 [eq(2)] = 9ml
or, x + y = 9ml.....(iii)
solving equations (i), (ii) and (iii)
z = 31 , x = 3 and y = 6
so, volume of CH4 = 6ml
% of CH4 in the original mixture = 6/40 × 100 = 15%.
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hey mate, your answer :
Let volume of CO, CH4 and Ne be x, y and z respectively.
CO + 1/2O2 CO2 .....(1)
here it is clear that x volume of CO reacts with x/2 volume of O2 and produces sx volume of CO2
and CH4 + 2O2 CO2 + 2H2O (l).....(2)
here it is clear that y volume of CH4 reacts with 2y volume of O2 and produces y volume of CO2.
now remaining volume of O2 = 10 - x/2 - 2y
volume after reaction,
volume of CO2 [eq(1)] + volume of CO2 [eq(2)] + volume of oxygen remaining + volume of Ne = 36.5 ml
or, x + y + 10 - x/2 - 2y + z = 36.5 ml
or, x/2 - y + z = 26.5 ml ......(i)
given, volume of Co + volume of CH4 + volume of Ne = 40ml
or, x + y + z = 40ml.....(ii)
we know, KOH reduces CO2
so, volume of CO2 [eq(1) ] + volume of CO2 [eq(2)] = 9ml
or, x + y = 9ml. (iii)
solving equations (i) (ii) and (iii)
z = 31 , x = 3 and y = 6
so, volume of CH4 = 6ml
% of CH4 in the original mixture = 6/40 × 100 = 15%
hope it helps u and Mark as the brainliest..
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