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Here is your today's question :-
Find the dimension of a & b in the following vanderwall equation. Here P - pressure, T - temperature, v - volume, R - gas constant.
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Explanation:
unit of a is atm L² mol–²
unit of b is L mol–¹
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P + a/V2) (V - b) = RT P is pressure, V is volume and T is temperature.
[P] = [F/A] = [MLT −2/L2] = [ML−1T −2] [V] = [L3]
We cannot add or subtract quantities of different dimensions.
Therefore [P] = [a/V2] ⇒ [a] = [PV2] = [ML−1T −2 L6] = [M L5 T −2] ∴ [a] = [M L5 T −2]
Similarly, [b] = [V] = [L3]
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