67
Calculate the enthalpy change
water at 10°C to ice at
10°C.
freezing of 1.0 mol of
6.03 kJ (nol
at 0°C
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Answer:
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Answered by
1
Answer:
Total enthalpy change involved in the transformation is the sum of the following changes and can be represented as :
According to Hess's law :
(ΔH)=(ΔH1)+(ΔH2)+(ΔH2)
(ΔH1)=(75.3Jmol−1K−1)(0−10)K=−753Jmol−1
(ΔH2)(solidification)=(−6.03×103Jmol−1)or60630Jmol−1
(ΔH3)−(36.8Jmol−1K−1)(−10−0)K=−368Jmol−1
Substituting the values we get
=−753Jmol−1=6030Jmol−1−368Jmol−1
=−56451Jmol−1
=−5.645kJmol−1
hence the enthalpy change involved in the transformation is −5.645kJmol−1
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