8. Calculate the equilibrium constant of the reaction when 8.1 mL of H2 and 9.3 mL of
12 react to form 13.5 mL of HI at 440°C.
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Answer:
25 ml of H2 and 18 ml of it paperwork heated in a sealed glass tube at 465 degree and at aquarium 30. 8 ml of HIV was formed calculate the percentage degree of dissociation of HIV at 465 degree c
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Given,
initial volume of H2 = 8.1 ml
initial volume of I2 = 9.3 ml
volume of HI = 13.5 ml
To find :
equilibrium constant .
Solution :
Let x be the dissociation .
From gas law , V is proportional to number of moles (const. T=440 C & P)
H2 + I2 -> 2HI
t=0 8.1 9.3 0
t=eq. 8.1-x 9.3-x 13.5
=> 2x = 13.5
=> x = 6.75
At equilibrium , volume of H2 = 8.1 - 6.75 = 1.35 ml
and , volume of I2 = 9.3 - 6.75 = 2.55 ml
Kc = [HI]^2/[H2] [I2]
Kc = 52.941
The equilibrium constant is 52.941
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