9. Give the chemical tests to distinguish between the following
pairs of compounds:
(i) Ethyl amine and Aniline
(ii) Aniline and Benzylamine
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Answer:
Aniline and Benzylamine
Explanation:
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Ethylamine and aniline
Azo dye test.
Aniline on diazotization ( ice cold nitrous acid solution) followed by coupling with 2-naphtol (in alkaline solution) forms brilliant orange or red dye. Ethylamine will not form dye. It will give brisk effervescence (due to liberation of nitrogen gas) but solution remains clear
Aniline and benzylamine
Azo dye test
Aniline on diazotization ( ice cold nitrous acid solution) followed by coupling with 2-naphtol (in alkaline solution) forms brilliant orange or red dye. Benzylamine will not give such test
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